Synergistic combination of sodium dodecane sulfonate and trietha-nolamine lauryl sulfate



FOAM VOLUMES l/V MLS.

Jan. 18, 1966 w. M. BRIGHT 3,230,174

SYNERGISTIC COMBINATION OF SODIUM DODECANE SULFONATE AND TRIETHANOLAMINELAURYL SULFATE Filed Aug. 2. 1960 20 Sheets-Sheet l CYLINDER FOAMVOLUMES OF SOD/UM OECANESULFO/VATE (SULFATE BUILT} AND LHES (SULFATEBU/LT}, SINGL) AND IN COMB/NAT/ON WITH EACH OTHER 30 SECONDS AF TE)?FOAM FORMATION Q V v V fij/ 6 2 v SQDIUM DECANE SULFONATE A)g...................... A la :5 l2 s e a o B 0 3 e 9 l2 I5 is ACTIVEINVENTOR. WILLARD M. BRIGHT Bi /M 4 Z,

hi AT T OfP/VE Y5 FOAM VOLUMES /N MLS Jan. 18, 1966 w. M. BRIGHT3,230,174

SYNERGISTIC COMBINATION OF SODIUM DODECANE SULFONATE AND Filed Aug. 2.1960 TRIETHANOLAMINE LAURYL SULFATE 2O Sheets-Sheet 2 CYLINDER FOAMVOLUMES 0F SOD/UM DECANESULFONATE (SULFATE BUILT), AND LHES (SULFAT EBUILT), SINGL) AND /N COMB/NATION W/TH EACH OTHER /5 MINUTES AFTER FOAMFORMAT/ON k A4" B AC ACTIVE F/Gf l5 INVENTOR. WILLARD M. BRIGHT @M/QIMAL hi5 ATTORNEYS FOAM VOLUMES IN MLS.

Jan. 18, 1966 w. BRlGHT 3,230,174

SYNERGISTIG COMBINATION OF SODIUM DODEGANE SULFONATE AND TRIETHANOLAMINELAURYL SULFATE Filed Aug. 2. 1960 20 SheetsSheet 5 OYL/NDEI? FOAMVOLUMES OF SOD/UM DODEOANESULFONATE(SULFATE BUILT} AND THES (SULFAT EBUILT}, SINGLY AND //V COMB/NAT/ON W/TH EACH OTHEI?- 30 SECONDS AFTERFOAM FORMAT/ON INVENTOR WILLARD M. BRIGHT BY 9 3w his AT T ORA/E Y8 FOAMVOLUMES IN MLS.

Jan. 18, 1966 W. M. BRIGHT SYNERGISTIC COMBINATION OF SODIUM DODECANESULFONATE AND TRIETHANOLAMINE LAURYL SULFATE Filed Aug. 2. 1960 20Sheets-Sheet 4 CYL/NDER FOAM VOLUMES OF SOD/UM DODECANESULFONATE{SULFATEBUILT) AND THES (SULFATE BUILT), S/NGLY AND IN COMB/NATION WITH EACHOTHER /5 MINUTES AF TEE FOAM FORMAT/ON SODIU M DODECANESULFOQIATE (A)ACTIVE FIG. 2B

INVENTOR. WLLARD M. BRIGHT 81 W ,Q/

his ATTORNEYS Jan. 18, 1966 w. M. BRIGHT 3,230,174

SYNERGISTIC COMBINATION OF SODIUM DODECANE SULFONATE AND TRIETHANOLAMINELAURYL SULFATE Filed Aug. 2. 1960 20 Sheets-Sheet 5 CYLINDER FOAMVOLUMES 0F SOD/UM OODECANESULFONATE PHOSPHATE BUILT) AND THES/PHOSPHATEBUILT), SINGLY AND /N COMB/NATION WITH EACH OTHER 30 SECONDS AFTER FOAMFORMAT/0N ACTUAL A+B) WILLARD M. BRIGHT W 12,

his ATTORNEYS Jan. 18, 1966 w. M. BRIGHT 3,230,174

SYNERGISTIC COMBINATION OF SODIUM DODECANE SULFONATE AND TRIETHANOLAMINELAURYL SULFATE Filed Aug. 2. 1960 20 Sheets-Sheet 6 CYLINDER FOAMVOLUMES OF SOD/UM DODEOA/VESULFONAT E (PHOSPHATE BUILT) A/VDTHES/PHOSPHATE BUILT), SINGLY AND IN COMB/NATION W/T H EACH OTHER /5MINUTES AF T El? FOAM FORMAT/ON FOAM VOLUMES l/V MLS i Q kpeclgPlif:-;:E1 y i t/ Om ..l.QQ'.'-. M..QQP Q L A is 9 6 a O B o 3 6 9 '5 '8ACTIVE INVENTOR. WILLARD M. BRIGHT BY fizz I /%M V his AT 7' ORA/E Y5FOAM VOLUMES IN MLS.

Jan. 18, 1966 w, m -r 3,230,174

SYNERGISTIG COMBINATION OF SODIUM DODECANE SULFONATE AND TRIETHANOLAMINELAURYL SULFATE Filed Aug. 2. 1960 20 Sheets-Sheet '7 CYLINDER FOAMVOLUMES OF SOD/UM DODECANESULFONATE/NON-BU/LT) AND THES (NON-BU/LT),SINGLY AND /N COMB/NATION WITH EACH OTHER.

30 SECONDS AF T ER FOAM FORMAT/ON Q 5 wfi z f)? T A 100 15 so 25 o B o25 5o 15 I00 ACTIVE INVEN TOR.

WILLARD M. BRIGHT his ATTORNEYS FOAAI VOLUWMZSAVIMZS Jan. 18, 1966 w. M.BRIGHT 3,230,174

SYNERGISTIC COMBINATION OF SODIUM DODECANE SULFONATE AND TRIETHANOLAMINELAURYL SULFATE Filed Aug. 2. 1960 20 Sheets-$heet 8 CYLINDER FOAMVOLUMES 0F SOD/UM DODECANESULFO/VATE {NON-BUILT) A/VD THES (NON-BUILT),SINGL) AND /N COMB/NATION W/TH EACH OTHER.

/5 MINUTES AFTER FOAM FORMAT/0N WILLARD M. BRIGHT his AT T DRIVE Y5 FOAMVOLUMES /N MLS.

Jan. 18, 1966 w -r 3,230,174

SYNERGISTIC COMBINATION OF SODIUM DODECANE SULFONATE AND TRIETHANOLAMINELAURYL SULFATE Filed Aug. 2. 1960 20 Sheets-Sheet 9 CYLINDER FOAMVOLUMES 0F SOD/UM DODECANESULFONATE SULFATE BUILT} AND LHES (SULFAT EBUILT SINCL) AND IN COMB/NAT ION W/T H EACH OTHER.

30 SECONDS AFTER FOAM FORMAT/0N INVENTOR. WILLARD M. BRIGHT BYQ A 13 hisATTORNEYS ACTIVE W. M. BRIGHT Jan. 18, 1966 TRIETHANOLAMINE LAURYLSULFATE 20 Sheets-Sheet 10 Filed Aug. 2. 1960 CYLINDER FOAM VOLUMES OFSOD/UM OOOECANESULFO/VATE (SULFATE BUILT) AND LHES (SULFATE BU/LT),SINGLY AND IN GOMB/NAT/O/V WITH EACH OTHER.

/5 MINUTES AF TER FOAM FORMAT/ON m E w M T w E :m M m o D L w w w M 0 nP e 0 O o m m 0 AB ACTIVE IN V EN TOR. WILLARD M. BRIGHT his AT T OR/VEY5 W. M. BRIGHT Jan. 18, 1966 SYNERGISTIC COMBINATION OF SODIUM DODECANESULFONATE AND TRIETHANOLAMINE LAURYL SULFATE 2O Sheets-Sheet 11 FiledAug. 2. 1960 H mm m0 LN UA fiv, M M mm m ML mllfi ml 1 R T10 0 EU F 75%M ME J.. m wflm f x F w R 5% how... 2 m M A 5 S H p M 0. N UDN -Q. 0 L0.. 0 O -E V MIIlPI MW, 5 )0 g/ 0 M 3 MW FB RE E7 0A 1 WM u 5 0 INVENTOR. WILLARD M. BRIGHT ACTIVE FIG. 6A

W. M. BRIGHT Jan, 18, 1966 SYNBRGISTIC COMBINATION OF SODIUM DODECANESULFONATE AND TRIETHANOLAMINE LAURYL SULFATE 2O Sheets-Sheet 12 FiledAug. 2. 1960 GYL/NDEI? FOAM VOLUMES 0F SOD/UM TE TRADECANESULFONATE(SULFATE Elf/L77 AND LHES {SULFATE BUILT), Sl/VGLY AND //V COMB/NATIONW/TH EACH OTHER /5 MINUTES AFTER FOAM FORMAT/0N MAR MMSSQQL 366k HO ABACTIVE INVENTOR.

WILLARD M. BRIGHT FIG 65 BY his Jan. 18, 1966 Filed Aug. 2. 1960 W. M.BRIGHT TE AND 20 Sheets-Sheet l5 CYLINDER FOAM VOLUMES 0F SOD/UMDODEGANESULFONATE //V0/V-BU/L7'/ AND STEPA/VOL WAT/ NON-BUILT}, S/NG'LYAND IN COMB/NATION WITH EACH OTHER.

30 SECONDS AFTER FOAM FORMAT/0N 'i I XQT/ x 0 x w 4, Q 0

l8 l5 l2 9 6 3 O O 3 6 9 l2 5 l8 ACTIVE INVENTOR. WlLLARD M. BRIGHT M 32 9 his ATTORNEYS FOAM VOLUMES IN MLS.

Jan. 18, 1966 SYNERGISTIC COMBINATION OF SODIUM DODECANE SULFONATE ANDTRIETHANOLAMINE LAURYL SULFATE Filed Aug. 2. 1960 w. M. BRIGHT 3,230,174

20 Sheets-Sheet l4 OYL/NOEI? FOAM VOLUMES OF SOD/UM OOOEOANESULFONATE(NON-BUILT) 4ND STEPANOL WAT (NON-BUILT), SINGLY AND /N OOMB/NAT/ON WITHEACH OTHER 15 MINUTES AFTER FOAM FORMAT/ON 5 STEPANOL WAT B SODIUMDODEQANESULFONA TE (A) ACTIVE IN VEN TOR.

WILLARD M. BRIGHT M :yJ-(L/ his AT T ORNE Y5 Jan. 18, 1966 Filed Aug. 2.1960 W. M. BRIGHT SYNERGISTIC COMBINATION OF SODIUM DODECANE SULFONATEAND TRIETHANOLAMINE LAURYL SULFATE 2O Sheets-Sheet l5 CYLINDER FOAMVOLUMES OF SOD/UM OODEOA/VESULFO/VATE (SULFATE BUILT} AND STEPANOL WAT{NON-BUILT}, Sl/VG'LY AND IN COMB/NATION W/ TH EACH OTHER.

FOAM VOLUMES //V MLSI 30 SECONDS AFTER FOAM FORMAT/ON ACTUAL HH-B)EXPECTE \k A/ g u T? WAT 3 a} u EEPANOL L 80 41 0 EL 4 o 4 4,

o a s 9 2 '5 a ACTIVE FIG 34 IN V EN TOR.

WILLARD M. BRIGHT his Jan. 18, 1966 w. M. BRIGHT 3,230,174

SYNERGISTIC COMBINATION OF SQDIUM DODECANE SULFONATE AND TRIETHANOLAMINELAURYL SULFATE Filed Aug. 2. 1960 20 Sheets-Sheet l6 OYL/NOER FOAMVOLUMES OF SOD/UM DOOEGANESULFONAT E (SULFATE BUILT) AND STEPANOL WAT(NON-BUILT), S/NGLY AND IN OOMB/NAT/ON W/TH EACH OTHER /5 MINUTES AFTEI? FOAM FORMAT/ON a}, 200 Q E ACT EXPEGTEE J A a STE'PANOL WAT(B) 4 LSODIUM DOQ ECANESULFONATE (A) A i8 l5 l2 9 6 3 O B o a s 9 12' :5 IB

% ACTIVE INVENTOR.

WILLARD M. BRIGHT BY M9452 his ATTORNEYS FOAM VOLUMES //V MLS.

Jan. 18, 1966 SYNERGISTIC COMBINATION OF SODIUM DODECANE SULFONATE ANDFiled Aug. 2. 1960 w. M. BRIGHT 3,230,174

TRIETHANOLAMINE LAURYL SULFATE 20 Sheets-Sheet 1'7 CYL W051? FOAMVOLUMES 0F SOD/UM 000E GANESULFO/VAT E (NON-BU/L 7' AND TRITON X /00{NOW -BU/LT), Sl/VGLY AND //V COMB/NAT ION W/ 7' H EACH OTHER 30 SECONDSAF TER FOAM FORMAT/0N ACTUAL (A+B) pA-B /g k "1 SODIUM DODECANESULFONATE"v I TRITON -I( 10048 a T .4)? n 2* I8 l5 l2 9 5 5 O 0 3 6 9 I2 l5 l8ACTIVE INVENTOR.

WILLARD M. BRIGHT BY fl his ATTORNEYS Jan. 18, 1966 w. M. BRIGHT3,230,174

SYNERGISTIC COMBINATION OF SODIUM DODECANE SULFONATE AND TRIETHANOLAMINELAURYL SULFATE Filed Aug. 2. 1960 20 Sheets-Sheet l8 CYLINDER FOAMVOLUMES OF SOD/UM OODEOA/VESULFO/VATE (/VO/V-BU/LT) AND T R/T 0N X /OO{NON-BULL T SINGL) AND M/ COMB/NATION W/T H EACH OTHER /5 MINUTES AFTEf? FOAM FORMAT/ON s 200 E a ACTUAL A+B) 5 F E. S E

EXP T \\D R! 3OO\ (B SODIUM DODEGANESULFONATE (A) g l A '8 l5 l2 9 6 3 OB 0 3 6 9 I2 IS IS ACTIVE INVENTOR.

WILLARD M. BRIGHT his AT T OEWE Y$ Jan. 18, 1966 w. M. BRIGHT 3,230,174

SYNERGISTIC COMBINATION OF SODIUM DODECANE SULFONATE AND TRIETHANOLAMINELAURYL SULFATE Filed Aug. 2. 1960 20 Sheets-Sheet l9 CYLINDER FOAMVOLUMES OF SOD/UM DODEOANESULFO/VATE NON BU/LT AND ARMEE/V (8D)(NON-BUILT), S/NGLY AND /N COMB/NAT ION W/T H EACH OTHER.

30 SECONDS AFTER FOAM FORMAT lO/V E 0 ACTUAL MB) E (I) lg 3 x"- g 4)FONM q New Q 100 E b [k M 009 ARMEEN (80MB) )k 4 A l8 l5 I2 9 6 3 0 B O3 6 9 I2 15 la 46 T IV IN V EN TOR. WILLARD M. BRIGHT 4WD? ML,

his ATTORNEYS Jan. 18, 1966 w. M. BRIGHT 3,230,174

SYNERGISTIG COMBINATION OF SODIUM DODECANE SULFONATE AND TRIETHANOLAMINELAURYL SULFATE Filed Aug. 2. 1960 20 Sheets-Sheet 20 CYLINDER FOAMVOLUME 5 OF SOD/UM DODECA/VESULFO/VATE (NON-BUILT) AND ARMEE/V/8D}/NO/V-BU/LT), S/NG'LY AND //V COMB/NAT/ON W/T H EACH OTHER /5MINUTES AF TE/P FOAM FORMAT/ON SODIUM DODECANESULFONATE (A) a" 200 4ARMEEN (8D) (8) a r 3 N, U) 8 g 3 S 5 E 100 EXPECTED (A+B) A 1a 15 I2 8o a s ACT/l/E INVENTOR. WILLARD M. BRIGHT W ea his AT TORNE K5

1. A SYNERGISTIC FOAMING COMPOSITION COMPRISING FROM ABOUT 2.5 TO ABOUT13.5 PARTS SODIUM DODECANE SULFONATE AND FROM ABOUT 15.5 TO ABOUT 4.5PART TRIETHANOLAMINE LAURYL SULFATE, RESPECTIVELY; SAID COMPOSITIONHAVING AN ACTUAL FOAM VOLUME AFTER 15 MINUTES AGING MORE THAN 35 ML.ABOVE THE EXPECTED FOAM VOLUME AND HAVING A